Le credenze precedenti sono state ribaltate dalla scoperta di strutture disposte in modo irregolare.
Per molti, la parola “cristalli” evoca immagini di raggi solari scintillanti che creano prismi dai colori dell’arcobaleno o pietre traslucide che si ritiene abbiano poteri curativi. Ma nella scienza e nell’ingegneria, i cristalli assumono una definizione più tecnica. Sono viste come sostanze i cui componenti – siano essi atomi, molecole o nanoparticelle – sono disposti regolarmente nello spazio. In altre parole, i cristalli sono identificati dalla disposizione regolare dei loro componenti. Esempi familiari includono diamanti, sale da tavola e zollette di zucchero.
Contrariamente a questa definizione ampiamente accettata, un recente studio condotto da Sangwoo Lee, Assistant Professor presso il Dipartimento di Ingegneria Chimica e Biologica del Rensselaer Polytechnic Institute, rivela un aspetto interessante delle strutture cristalline, rivelando che la disposizione dei componenti all’interno dei cristalli non lo è. Sempre necessariamente regolare.
Questa scoperta fa avanzare il campo della scienza dei materiali e ha implicazioni non realizzate per i materiali utilizzati in essa[{” attribute=””>semiconductors, solar panels, and electric vehicle technologies.
One of the most common and important classes of crystal structures is the close-packed structures of regular spheres constructed by stacking layers of spheres in a honeycomb arrangement. There are many ways to stack the layers to construct close-packed structures, and how nature selects specific stacking is an important question in materials and physics research. In the close-packing construction, there is a very unusual structure with irregularly spaced constituents known as the random stacking of two-dimensional hexagonal layers (RHCP). This structure was first observed from cobalt metal in 1942, but it has been regarded as a transitional and energetically unpreferred state.
Lee’s research group collected X-ray scattering data from soft model nanoparticles made of polymers and realized that the scattering data contains important results about RHCP but is very complicated. Then, Patrick Underhill, professor in Rensselaer’s Department of Chemical and Biological Engineering, enabled the analysis of the scattering data using the supercomputer system, Artificial Intelligence Multiprocessing Optimized System (AiMOS), at the Center for Computational Innovations.
“What we found is that the RHCP structure is, very likely, a stable structure, and this is the reason that RHCP has been widely observed in many materials and naturally occurring crystal systems,” said Lee. “This finding challenges the classical definition of crystals.”
The study provides insights into the phenomenon known as polytypism, which enables the formation of RHCP and other close-packed structures. A representative material with polytypism is silicon carbide, widely used for high-voltage electronics in electric vehicles and as hard materials for body armor. Lee’s team’s findings indicate that those polytypic materials may have continuous structural transitions, including the non-classical random arrangements with new useful properties.
“The problem of how soft particles pack seems straightforward, but even the most basic questions are challenging to answer,” said Kevin Dorfman of the University of Minnesota-Twin Cities, who is unaffiliated with this research. “This paper provides compelling evidence for a continuous transition between face-centered cubic (FCC) and hexagonal close-packed (HCP) lattices, which implies a stable random hexagonal close-packed phase between them and, thus, makes an important breakthrough in materials science.”
“I am particularly pleased with this discovery, which shows the power of advanced computation to make an important breakthrough in materials science by decoding the molecular level structures in soft materials,” said Shekhar Garde, dean of Rensselaer’s School of Engineering. “Lee and Underhill’s work at Rensselaer also promises to open up opportunities for many technological applications for these new materials.”
Reference: “Continuous transition of colloidal crystals through stable random orders” by Juhong Ahn, Liwen Chen, Patrick T. Underhill, Guillaume Freychet, Mikhail Zhernenkovc and Sangwoo Lee, 14 April 2023, Soft Matter.
DOI: 10.1039/D3SM00199G
Lee and Underhill were joined in research by Rensselaer’s Juhong Ahn, Liwen Chen of the University of Shanghai for Science and Technology, and Guillaume Freychet and Mikhail Zhernenkov of Brookhaven National Laboratory.
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